Search results for "Optical materials"
showing 10 items of 31 documents
Synthesis and characterization of chalcogenide glasses from the system Ga-Ge-Sb-S and preparation of a single-mode fiber at 1.55 μm
2008
International audience; The aim of this work is to study different compositions in the Ga-Ge-Sb-S system for the definition of two compositions compatible with the elaboration of a single-mode fiber at the 1.55 μm telecom wavelength. The variations of the glass transition temperature (Tg), the dilatation coefficient (α) and the refractive index (n) have been studied for two glasses series: GaxGe25−xSb10S65 (series 1), Ga5Ge25−xSb10S60+x (series 2). This study has lead to the choice of the Ga4Ge21Sb10S65 composition as clad glass for the preparation of the single-mode fiber and Ga5Ge20Sb10S65 composition as the core. The discrepancies for the studied parameters between the core and clad comp…
First‐principles modeling of the H color centers in MgF 2 crystals
2012
MgF2 with a rutile structure is important wide-gap optical material with numerous applications. We present and discuss the results of calculations for basic hole defects – interstitial F atoms (called also the colour H centers). This study is based on the large scale ab initio DFT calculations using hybrid B3PW exchange-correlation functional as implemented into CRYSTAL computer code. The electronic structure, atomic geometry, charge density distribution are calculated and compared with similar defects in CaF2 fluorite. It is shown that the H centers oriented nearly parallel to the (110) axis are energetically more favourable than those oriented along the (001) axis, in agreement with exper…
<title>Manifestation of structural features in Raman spectra of LiNbO<formula><inf><roman>3</roman></inf></for…
2008
Raman studies of ostensibly pure congruent, close to stoichiometric and stoichiometric lithium niobate single crystals and single crystals of lithium niobate containing admixture of Gd3+, Y+, and Mg2+ are reported. The authors have revealed weak Raman bands anomalously narrowing at changes of crystal composition disordering the cation sublattice and discuss the results with regard to evidence of anomalous ordering of structural units of the cation sublattice occurring at disordering of the cation sublattice as a whole.© (2008) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
Linear and nonlinear optical properties of a series of Ni-dithiolene derivatives
2009
Some linear and nonlinear optical (NLO) properties of Ni(SCH)4 and several of its derivatives have been computed by employing a series of basis sets and a hierarchy of methods (e.g., HF, DFT, coupled cluster, and multiconfigurational techniques). The electronic structure of Ni(SCH)4 has been also analyzed by using CASSCF/CASPT2, ab initio valence bond, and DFT methods. In particular we discuss how the diradicaloid character (DC) of Ni(SCH)4 significantly affects its NLO properties. The quasidegeneracy of the two lowest-energy singlet states 1 mathg and 1 math1u, the clear DC nature of the former, and the very large number of low-lying states enhance the NLO properties values. These particul…
Opals infiltrated with a stimuli-responsive hydrogel for ethanol vapor sensing
2013
We report on a novel class of optical materials for ethanol vapor sensing, based on polystyrene opals infiltrated with an innovative stimuli responsive hydrogel. We describe the fabrication process of the bare polystyrene opals and their subsequent infiltration. The optical characterization of the photonic crystal templates was performed to prove the good quality of the samples. Measurements on the infiltrated opals showed that the transmission spectra in the visible range strongly change at varying concentrations of ethanol vapor. The fabricated structures show a linear optical response in the visible range, for high values of ethanol concentration.
Reactivity of SiCl and SiF groups in SiO2 glass with mobile interstitial O2 and H2O molecules
2007
Reactions of common network-bound halogens in synthetic SiO2 glass, SiCl and SiF groups, with interstitial O2 and H2O molecules incorporated by thermally annealing were studied. It was found that the chemical properties are distinctly different between SiCl and SiF groups. SiCl groups react with interstitial O2 and H2O to form interstitial Cl2 and HCl, respectively. In contrast, formation of interstitial F2 and HF due to the reaction of SiF groups with interstitial O2 and H2O is not observed. The reactivity of SiCl and SiF groups is in accord with the properties and thermodynamic data of their respective analogous compounds, SiCl4 and SiF4.
Chalcogenide Glasses Based on Germanium Disulfide for Second Harmonic Generation
2007
International audience; High second-order susceptibilities are created by thermal poling in bulk germanium disulfide based chalcogenide glasses. Experimental conditions of the poling treatment (temperature, voltage, time) were optimized for each glass composition. The second-order nonlinear signals were recorded by using the Maker fringes experiment and a second-order coefficient χ(2) up to 8 pm V-1 was measured in the Ge25Sb10S65 glass. This value is obtained using a simulation based on accurate knowledge of the thickness of the nonlinear layer. Two mechanisms are proposed to explain the creation of a nonlinear layer under the anode: the formation and the migration of charged defects towar…
Biomineral Amorphous Lasers through Light-Scattering Surfaces Assembled by Electrospun Fiber Templates
2018
New materials aim at exploiting the great control of living organisms over molecular architectures and minerals. Optical biomimetics has been widely developed by microengineering, leading to photonic components with order resembling those found in plants and animals. These systems, however, are realized by complicated and adverse processes. Here we show how biomineralization might enable the one-step generation of components for amorphous photonics, in which light is made to travel through disordered scattering systems, and particularly of active devices such as random lasers, by using electrospun fiber templates. The amount of bio-enzymatically produced silica is related to light-scatterin…
Optical and morphological properties of infrared emitting functionalized silica nanoparticles
2013
Abstract The loading process of functionalized silica nanoparticles was investigated in order to obtain nanoparticles having functional groups on their surface and Near-Infrared (NIR) emission properties. The NIR emission induced by O 2 loading was studied in silica nanoparticles, produced by pyrogenic and microemulsion methods, with size ranging from 20 to 120 nm. Loading was carried out by thermal treatments in O 2 atmosphere up to 400 °C and 90 bar. The effects of the thermal treatments on the NIR emission and on the structural properties were studied by luminescence and Raman techniques, whereas the morphological features were investigated by Transmission Electron Microscopy and Atomic …
Dispersion managed self-similar parabolic pulses
2008
International audience; We describe the propagation of a parabolic self-similar pulse in an anomalous dispersive nonlinear fibre. Given the capacity of a linearly chirped parabolic pulse to retain its typical shape over a short propagation distance, we introduce the concept of dispersion managed self-similar pulses and outline potential benefits in terms of spectral broadening enhancement.